Hydrocarbons/unit-13

Hydrocarbons:

Hydrocarbons are compounds containing carbon and hydrogen only. Depending upon the type of carbon—carbon bonds present, hydrocarbon can be classified into three main categories viz,

  •   Saturated Hydrocarbons
  •   Unsaturated Hydrocarbons
  •   Aromatic Hydrocarbons

1) Saturated Hydrocarbons:

The hydrocarbons which contain only carbon—carbon single bonds are called saturated hydrocarbons. These include open chain hydrocarbons as well as closed chain (cyclic) hydrocarbons. For examples, alkanes and cycloalkanes.

CH4                      CH3—CH3            CH3—CH2—CH3           CH3—CH2—CH2—CH3          Methane            Ethane                   Propane                             Butane

2) Unsaturated Hydrocarbons:

The hydrocarbons which contain carbon-carbon multiple bonds (double or triple bonds or both) are called unsaturated hydrocarbons. Depending upon the multiple bonds (double or triple bonds) they are classified as alkenes and alkynes.

Alkenes are hydrocarbons which contain at least one carbon—carbon double bond. e.g.

CH2 = CH2                     CH2 == CH—CH3                   CH3—CH = CH—CH3

Ethene                             Propene                                      Butene

Alkynes are hydrocarbons which contain at least one carbon—carbon triple bond. e.g.

CH ≡ CH                                CH ≡≡C—CH3                        CH3—C ≡ C—CH3

Ethyne                                Propyne                                      Butyne

3) Aromatic Hydrocarbons:

Aromatic hydrocarbons are those which contain at least one special type of hexagonal ring of carbon atoms with three double bonds in the alternate positions. The ring is called aromatic ring or benzene ring. For examples,

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