Standard Electrode Potential:
Standard electrode potential of a metal is defined as the potential difference developed in a cell consisting of two electrodes, the pure metal being in contact with a molar solution of one of its ions and the standard or normal hydrogen electrode.
If S.H.E acts as Anode, H2 (g) ——> 2H+ + 2e–
If S.H.E acts as cathode, 2H+ + 2e– ——-> H2 (g)